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(a) Wherever possible, these citations are drawn from original research. In many cases, however, the only source of information we had available was from a compilation of experimental data, with references to multiple original sources; in these instances, the citation listed here is to the compilation. For full bibliographical information, click on the footnote of interest. ![]()
(b) We have grouped this data into six basic categories: Critical surface tension as determined by the Zisman method (regression of the cosine of the contact angle), or by the wetting tension method (using solutions of 2-ethoxyethanol and formamide, per ASTM Std. D-2578); contact angle measurement; direct measurement of the surface tension of the polymer melt, extrapolated to 20o-25oC; calculated from various molecular and thermodynamic constants; other methods which do not fit clearly into any of the above; and data whose derivation is unknown. The contact angle section is divided into two subsections — the first lists actual contact angles with water, and the second shows surface energy and critical surface tension estimates calculated from the contact angles of various test liquids. ![]()
(c) Data is presented either as contact angle in degrees, critical surface tension in mJ/m2, or surface free energy in mJ/m2. Definitions of symbols follow. ![]()
#ϒsd Dispersion contribution to surface free energy. ![]()
#ϒsp Polar contribution to surface free energy. ![]()
#ϒsLW Lifschitz—van der Waals (non-polar) contribution to surface free energy (acid—base analysis). ![]()
#ϒsAB Interaction contribution to surface free energy (acid—base analysis). ![]()
#ϒs+ Acid contribution to surface free energy (acid—base analysis). ![]()
#ϒs- Base contribution to surface free energy (acid—base analysis). ![]()
ΘWY Equilibrium (or Young's) contact angle. ![]()
(d) This data is provided for review purposes; however, because it is a statistical outlier, compared to other reported values, it is not included in the summary table. ![]()
(e) The polar and dispersive contributions are provided for review purposes; however, because they are statistical outliers, compared to other reported values, they are not included in the summary table. ![]()