Critical Surface Tension Components (descending cse sort)

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This table highlights the critical surface tension, surface free energy, contact angles with water, and Hansen Solubility Parameters with interaction radius for a variety of polymers. For all columns except polymer name, CAS #, change in surface tension per degree Celsius (dγ/dt), and total Hansen Solubility Parameter (δ) the first row of data for each material is the average of surveyed values; the second row shows the standard deviation, with the number of data points (n) in parentheses. For n = 1, no standard deviation figure is shown. Click on any column's footnote for details. Click on any polymer name for original research results. An analogous table, which shows polar/dispersion and acid—base components of surface energy, can be seen here. Comments on methodology and the like can be found here.

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Critical Surface Tension, Surface Free Energy, Contact Angles with Water, and Hansen Solubility Parameters for Various Polymers

Name⁽¹⁾	CAS #⁽²⁾	γ_c⁽³⁾	γ_S⁽⁴⁾	dγ/dt⁽⁵⁾	θ_W^Y⁽⁶⁾	θ_W^A⁽⁷⁾	θ_W^R⁽⁸⁾	dθ_W ⁽⁹⁾	δ⁽¹⁰⁾	δ_D⁽¹¹⁾	δ_P⁽¹²⁾	δ_H⁽¹³⁾	R_o⁽¹⁴⁾
Thermoplastic polyolefin (TPO)	-	-	30.9	-	-	101.5	79.0	22.5	-	-	-	-	-
Thermoplastic polyolefin (TPO)			3.45(11)			3.54(2)	7.07(2)	3.54(2)
Polyxylylene (parylene)	-	-	46.3	-	-	-	-	-	-	-	-	-	-
Polyxylylene (parylene)			-(1)
Polyvinylidene fluoride (PVDF)	24937-79-9	31.6	31.5	-	86.0	93.4	91.0	1.0	23.2	17.0	12.1	10.2	4.1
Polyvinylidene fluoride (PVDF)		5.83(5)	5.29(13)		4.00(3)	1.98(2)	-(1)	-(1)		-(1)	-(1)	-(1)	-(1)
Polyvinylidene chloride (PVDC, Saran)	9002-85-1	40.2	43.7	-	80.0	-	-	-	23.1	19.0	9.6	9.0	5.8
Polyvinylidene chloride (PVDC, Saran)		3.89(4)	2.81(9)		-(1)					1.98(2)	0.64(2)	1.70(2)	2.62(2)
Polyvinyl pyrrolidone (PVP)	9003-39-8	-	46.0	-	-	-	-	-	-	-	-	-	-
Polyvinyl pyrrolidone (PVP)			3.61(2)
Polyvinyl formal	63450-15-7	39.0	-	-	-	-	-	-	-	-	-	-	-
Polyvinyl formal		-(1)
Polyvinyl fluoride (PVF)	24981-14-4	32.7	36.4	-	82.5	88.6	-	-	-	-	-	-	-
Polyvinyl fluoride (PVF)		4.66(4)	4.07(14)		3.54(2)	-(1)
Polyvinyl ethyl ether (polyethoxyethylene)	25104-37-4	-	36.0	-	-	-	-	-	-	-	-	-	-
Polyvinyl ethyl ether (polyethoxyethylene)			-(1)
Polyvinyl chloride (PVC)	9002-86-2	37.9	40.1	-	83.2	91.9	75.3	-	20.0	16.8	8.9	6.1	8.5
Polyvinyl chloride (PVC)		7.05(11)	3.66(22)		10.3(8)	7.88(3)	-(1)			1.65(5)	1.95(5)	1.78(5)	3.94(5)
Polyvinyl butyral	63148-65-2	28.0	38.0	-	-	-	-	-	24.6	19.1	9.5	12.2	10.0
Polyvinyl butyral		-(1)	-(1)							0.92(3)	4.50(3)	1.65(3)	1.53(3)
Polyvinyl alcohol (PVOH)	25213-24-5	37.0	44.2	-	51.0	-	-	-	25.2	14.7	14.1	14.9	10.5
Polyvinyl alcohol (PVOH)		-(1)	6.56(4)		-(1)					2.51(4)	2.13(4)	2.18(4)	1.38(4)
Polyurethanes	-	-	37.5	-	77.5	83.1	35.5	47.4	22.8	18.8	10.0	8.2	9.8
Polyurethanes			4.01(11)		7.52(8)	14.2(9)	16.3(9)	21.7(9)		1.53(11)	2.54(11)	3.09(11)	3.48(11)
Polytrifluoroethylene	24980-67-4	26.5	26.5	-	92.0	-	-	-	-	-	-	-	-
Polytrifluoroethylene		3.99(3)	2.79(7)		-(1)
Polytetramethylene oxide	-	-	32.8	-	-	-	-	-	-	-	-	-	-
Polytetramethylene oxide			1.27(2)
Polytetrahydrofuran (PTHF)	25190-06-1	-	31.9	-	-	-	-	-	-	-	-	-	-
Polytetrahydrofuran (PTHF)			0.00(2)
Polysulfone (PSU)	25135-51-7	42.1	44.9	-	75.0	66.0	-	-	21.5	18.5	8.5	7.0	9.4
Polysulfone (PSU)		1.48(2)	2.47(2)		-(1)	-(1)				2.17(3)	2.61(3)	1.12(3)	1.69(3)
Polystearyl methacrylate	25639-21-8	20.8	36.3	-	-	-	-	-	-	-	-	-	-
Polystearyl methacrylate		-(1)	-(1)
Poly(phosphazene)	-	16.5	15.8	-	-	-	-	-	-	-	-	-	-
Poly(phosphazene)		-(1)	0.35(2)
Polyphenylene sulfide (PPS)	26125-40-6	38.0	46.8	-	80.3	-	-	-	19.8	18.7	5.3	3.7	6.7
Polyphenylene sulfide (PPS)		-(1)	3.29(3)		1.53(3)					-(1)	-(1)	-(1)	-(1)
Polyphenylene oxide (PPO)	25134-01-4	47.0	46.0	-	-	-	-	-	19.3	16.9	8.9	2.7	11.7
Polyphenylene oxide (PPO)		-(1)	-(1)							-(1)	-(1)	-(1)	-(1)
Polyphenyl methacrylate	-	35.0	-	-	-	-	-	-	-	-	-	-	-
Polyphenyl methacrylate		-(1)
Polyoxymethylene (POM, polyacetal, polymethylene oxide)	24969-26-4	37.0	38.6	-	74.5	79.0	54.0	25.0	-	-	-	-	-
Polyoxymethylene (POM, polyacetal, polymethylene oxide)		1.41(2)	5.68(3)		-(1)	-(1)	-(1)	-(1)
Polyoctyl methacrylate	-	23.5	-	-	-	-	-	-	-	-	-	-	-
Polyoctyl methacrylate		-(1)
Poly(nonafluoroisobutyl acrylate)	-	-	14.0	-	-	-	-	-	-	-	-	-	-
Poly(nonafluoroisobutyl acrylate)			-(1)
Polymethylphenylsilylene	-	-	43.7	-	-	-	-	-	-	-	-	-	-
Polymethylphenylsilylene			0.57(2)
Polymethylphenylsiloxane	9005-12-3	-	26.1	-	-	-	-	-	-	-	-	-	-
Polymethylphenylsiloxane			-(1)
Poly(4-methyl pentene-1)	-	-	25.0	-	-	-	-	-	-	-	-	-	-
Poly(4-methyl pentene-1)			-(1)
Polymethacrylonitrile (PMAN)	25067-61-2	39.0	42.3	-	-	-	-	-	23.7	17.2	14.4	7.6	3.8
Polymethacrylonitrile (PMAN)		-(1)	3.08(3)							-(1)	-(1)	-(1)	-(1)
Polylauryl methacrylate	25719-52-2	21.3	32.8	-	-	-	-	-	-	-	-	-	-
Polylauryl methacrylate		-(1)	-(1)
Polyisoprene (PIP)	9003-31-0	-	32.3	-	-	-	-	-	18.4	18.1	2.4	2.3	10.3
Polyisoprene (PIP)			1.53(3)							2.32(3)	1.40(3)	2.66(3)	3.40(3)
Polyimide (PI)	25038-81-7	-	43.8	-	71.5	79.9	48.0	31.3	-	-	-	-	-
Polyimide (PI)			6.80(4)		2.07(6)	5.01(8)	12.2(8)	10.4(8)
Poly(2-hydroxyethyl methacrylate)	24249-16-5	37.0	-	-	-	-	-	-	-	-	-	-	-
Poly(2-hydroxyethyl methacrylate)		-(1)
Poly(hexafluoropropylene)	-	16.9	15.9	-	112.0	-	-	-	-	-	-	-	-
Poly(hexafluoropropylene)		0.96(3)	2.67(4)		-(1)
Poly(hexachlorobutadiene)	-	-	41.5	-	-	-	-	-	-	-	-	-	-
Poly(hexachlorobutadiene)			-(1)
Poly(heptafluoroisopropyl methacrylate)	-	-	15.0	-	-	-	-	-	-	-	-	-	-
Poly(heptafluoroisopropyl methacrylate)			-(1)
Poly(heptafluoroisopropyl acrylate)	-	-	14.0	-	-	-	-	-	-	-	-	-	-
Poly(heptafluoroisopropyl acrylate)			-(1)
Poly(heptadecafluorooctyl methacrylate)	-	-	15.3	-	-	-	-	-	-	-	-	-	-
Poly(heptadecafluorooctyl methacrylate)			-(1)
Polyethersulfone (PES)	25154-01-2	-	47.0	-	68.5	-	-	-	21.0	18.3	8.2	6.4	6.3
Polyethersulfone (PES)			-(1)		0.71(2)					0.91(6)	3.10(6)	2.33(6)	2.61(6)
Polyetherimide (PEI)	61128-46-9	-	-	-	76.5	-	-	-	19.8	17.7	6.0	6.4	4.8
Polyetherimide (PEI)					12.0(2)					1.07(5)	1.14(5)	2.43(5)	1.70(5)
Polyetheretherketone (PEEK)	29658-26-2	-	42.1	-	91.0	85.0	55.0	30.0	-	-	-	-	-
Polyetheretherketone (PEEK)			-(1)		-(1)	-(1)	-(1)	-(1)
Polyepichlorohydrin	24969-06-0	35.0	43.2	-	-	-	-	-	-	-	-	-	-
Polyepichlorohydrin		0.00(2)	-(1)
Poly(dimethylaminoethyl methacrylate)	-	-	36.0	-	-	-	-	-	-	-	-	-	-
Poly(dimethylaminoethyl methacrylate)			-(1)
Polybutylene terephthalate (PBT)	26062-94-2	-	46.3	-	-	84.0	-	-	-	-	-	-	-
Polybutylene terephthalate (PBT)			0.51(5)			0.00(2)
Polybenzyl methacrylate (PBMA)	25085-83-0	36.0	-	-	-	-	-	-	-	-	-	-	-
Polybenzyl methacrylate (PBMA)		-(1)
Poly(L-alanine)	25191-17-7	-	45.2	-	-	-	-	-	-	-	-	-	-
Poly(L-alanine)			-(1)
Polyacrylonitrile (PAN)	25014-41-9	47.0	46.8	-	-	-	-	-	27.4	21.7	14.1	9.1	10.9
Polyacrylonitrile (PAN)		4.24(2)	6.62(4)							-(1)	-(1)	-(1)	-(1)
Polyacrylamide	9003-05-8	34.3	52.3	-	-	-	-	-	-	-	-	-	-
Polyacrylamide		4.60(2)	-(1)
Polyacetylene (polyethyne)	-	-	51.5	-	72.0	-	-	-	-	-	-	-	-
Polyacetylene (polyethyne)			0.71(2)		-(1)
Phenoxy resin	26402-79-9	-	43.0	-	-	-	-	-	-	-	-	-	-
Phenoxy resin			-(1)
Nylon 12	24937-16-4	37.1	39.3	-	-	72.4	56.5	20.5	22.2	18.5	8.1	9.1	6.3
Nylon 12		8.63(2)	3.02(3)			5.37(3)	-(1)	-(1)		-(1)	-(1)	-(1)	-(1)
Nylon 11	25587-80-8	35.6	34.0	-	-	82.0	-	-	20.5	17.0	4.4	10.6	5.1
Nylon 11		4.40(8)	-(1)			9.90(2)				-(1)	-(1)	-(1)	-(1)
Nylon 10,10	-	32.0	-	-	-	94.0	-	-	-	-	-	-	-
Nylon 10,10		-(1)				-(1)
Nylon 9,9	-	34.0	-	-	-	86.0	-	-	-	-	-	-	-
Nylon 9,9			-(1)				-(1)
Nylon 8,8	-	34.0	-	-	-	86.0	-	-	-	-	-	-	-
Nylon 8,8		-(1)				-(1)
Nylon 7,7	-	43.0	-	-	-	70.0	-	-	-	-	-	-	-
Nylon 7,7		-(1)				-(1)
Nylon 6,12	24936-74-1	-	67.0	-	-	-	-	-	-	-	-	-	-
Nylon 6,12			-(1)
Nylon 6,10	9008-66-6	-	40.5	-	-	71.0	-	-	-	-	-	-	-
Nylon 6,10			-(1)			-(1)
Nylon 6 (polycaprolactum, aramid 6)	25038-54-4	43.9	45.4	-	-	65.5	42.4	26.8	20.3	17.0	3.4	10.6	5.1
Nylon 6 (polycaprolactum, aramid 6)		2.42(3)	3.52(6)			4.27(7)	-(1)	-(1)		-(1)	-(1)	-(1)	-(1)
Nylon 4	24938-56-5	-	48.5	-	-	-	-	-	-	-	-	-	-
Nylon 4			-(1)
Nylon 2 (polyglycine)	25718-94-9	-	50.1	-	-	-	-	-	-	-	-	-	-
Nylon 2 (polyglycine)			-(1)
Nitrocellulose (cellulose nitrate)	9004-70-0	-	42.7	-	-	54.7	20.0	34.7	23.5	16.2	14.1	9.5	10.7
Nitrocellulose (cellulose nitrate)			4.10(3)			11.0(3)	22.5(3)	12.1(3)		1.06(2)	0.85(2)	1.06(2)	1.13(2)
Nafion	31175-20-9	-	-	-	-	90.5	-	-	-	-	-	-	-
Nafion						4.80(4)
2-Hydroxyethyl methacrylate (HEMA, ethylene glycol monoacrylate)	867-77-9	-	56.8	-	-	59.0	-	-	-	-	-	-	-
		1.20(2)			-(1)
Fluorinated ethylene polypropylene (FEP)	25067-11-2	19.1	18.5	-	105.7	112.7	98.5	14.8	19.6	19.0	4.0	3.0	4.0
Fluorinated ethylene polypropylene (FEP)		1.27(2)	2.25(7)		4.54(6)	5.03(4)	5.28(4)	1.31(3)		-(1)	-(1)	-(1)	-(1)
Ethylene-propylene-diene-monomer (EPDM)	25038-36-2	-	32.5	-	91.0	-	-	-	-	-	-	-	-
Ethylene-propylene-diene-monomer (EPDM)		4.31(2)		-(1)
Ethyl methacrylate (EMA)	97-63-2	-	42.0	-	-	74.0	-	-	-	-	-	-	-
Ethyl methacrylate (EMA)			1.06(2)			-(1)
Ethyl cellulose	9004-57-3	-	30.3	-	-	84.5	-	-	20.4	19.0	5.6	4.9	7.9
Ethyl cellulose			2.40(2)			-(1)				1.56(2)	1.84(2)	1.41(2)	2.83(2)
Epoxies	-	44.5	45.3	-	54.0	87.5	-	-	24.1	19.2	10.9	9.6	11.1
Epoxies		0.71(2)	4.21(6)		-(1)	3.54(2)				2.53(13)	2.37(13)	2.66(13)	3.98(13)
Cellulose triacetate	9012-09-3	48.8	-	-	-	-	-	-	-	-	-	-	-
Cellulose triacetate		-(1)
Cellulose acetate butyrate (CAB)	9004-36-8	-	34.0	-	-	-	-	-	22.2	17.2	13.8	2.8	12.6
Cellulose acetate butyrate (CAB)			-(1)							-(1)	-(1)	-(1)	-(1)
Cellulose acetate (CA)	9004-35-7	37.5	41.1	-	54.5	-	-	-	23.5	17.1	13.1	9.4	10.6
Cellulose acetate (CA)		2.12(2)	3.37(5)		-(1)					1.58(4)	4.41(4)	3.81(4)	2.96(4)
Cellophane	9005-81-6	-	45.4	-	-	-	-	-	28.5	16.1	18.5	14.5	9.3
Cellophane			-(1)							-(1)	-(1)	-(1)	-(1)
Aramid (Kevlar)	26125-61-1	-	45.7	-	-	63.7	-	-	-	-	-	-	-
Aramid (Kevlar)			1.76(3)			3.54(2)
Amorphous fluoropolymer (Teflon AF)	-	-	-	-	-	117.5	90.3	27.1	-	-	-	-	-
Amorphous fluoropolymer (Teflon AF)						5.67(5)	3.42(5)	9.13(5)
Aluminum foil ^(f)	7429-90-5	-	41.2	-	81.3	-	-	-	-	-	-	-	-
Aluminum foil ^(f)			2.47(2)		4.60(2)	-	-	-	-	-	-	-	-
Acrylonitrile butadiene styrene (ABS)	9003-56-9	38.5	42.0	-	89.7	72.0	-	-	19.2	17.0	5.7	6.8	9.4
Acrylonitrile butadiene styrene (ABS)		-(1)	4.70(8)		-(1)	-(1)				0.92(2)	4.17(2)	0.49(2)	2.19(2)
Polydimethylsiloxane (PDMS)	9016-00-6	20.1	20.4	-0.048^(b)	107.8	107.0	69.1	39.3	-	-	-	-	-
Polydimethylsiloxane (PDMS)		3.17(7)	1.54(26)		8.78(3)	4.44(9)	7.10(7)	3.73(7)
Polyvinyl octanoate	-	-	28.7	-0.061^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl octanoate			-(1)
Polyvinyl hexanoate	-	-	28.9	-0.063^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl hexanoate			-(1)
Polyvinyl dodecanoate	-	-	29.1	-0.063^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl dodecanoate
Polyvinyl decanoate	-	-	28.9	-0.062^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl decanoate			-(1)
Polytetrafluoroethylene (PTFE)	9002-84-0	19.4	21.8	-0.058^(c)	109.4	108.9	96.0	14.3	16.7	16.2	1.8	3.4	3.9
Polytetrafluoroethylene (PTFE)		1.49(8)	3.24(35)		5.70(17)	7.06(8)	8.72(3)	10.6(3)		-(1)	-(1)	-(1)	-(1)
Polypropylene (PP)	^(a)	30.5	30.2	-0.058^(b)	94.9	107.3	89.0	20.2	18.0	17.7	2.9	1.2	6.2
Polypropylene (PP)		1.50(3)	2.77(32)		5.29(11)	7.75(15)	5.73(6)	2.72(6)		0.46(2)	2.80(2)	1.71(2)	1.76(2)
Poly a-methyl styrene	25014-31-7	-	38.7	-0.058^(b)	-	-	-	-	-	-	-	-	-
Poly a-methyl styrene			-(1)
Polyisobutylene (PIB, butyl rubber)	9003-27-4	27.0	33.2	-0.064^(b)	-	112.1	-	-	17.1	16.4	1.7	4.7	7.9
Polyisobutylene (PIB, butyl rubber)		0.00(2)	3.21(10)			-(1)				1.26(6)	2.15(6)	2.08(6)	2.46(6)
Poly(hexyl methacrylate)	25087-17-6	27.5	30.0	-0.062^(c)	-	-	-	-	-	-	-	-	-
Poly(hexyl methacrylate)		-(1)	0.00(2)
Polyethylene (PE)	9002-88-4	31.6	33.5	-0.057^(b)	94.9	97.2	83.1	13.9	17.6	16.8	3.8	3.8	6.6
Polyethylene (PE)		2.05(21)	3.02(62)		6.96(27)	5.80(26)	10.7(9)	8.66(9)		0.88(7)	1.94(7)	2.52(7)	2.84(7)
Poly 2-ethylhexyl methacrylate	25719-51-1	-	28.8	-0.062^(c)	-	-	-	-	-	-	-	-	-
Poly 2-ethylhexyl methacrylate			-(1)
Polycarbonate (PC)	24936-68-3	44.0	42.3	-0.060^(c)	81.3	84.0	68.0	16.0	22.2	19.6	8.8	5.7	10.2
Polycarbonate (PC)		2.83(2)	5.32(7)		5.77(3)	-(1)	-(1)	-(1)		1.75(3)	2.58(3)	1.04(3)	4.06(3)
Poly t-butyl methacrylate (PtBMA)	25189-00-9	18.1	30.5	-0.059^(b)	108.1	-	-	-	-	-	-	-	-
Poly t-butyl methacrylate (PtBMA)		-(1)	0.00(2)		-(1)
Poly n-butyl methacrylate (PnBMA)	25608-33-7	29.8	33.1	-0.059^(b)	91.0	-	-	-	18.4	16.0	6.2	6.6	9.5
Poly n-butyl methacrylate (PnBMA)		1.94(3)	2.70(12)		-(1)					-(1)	-(1)	-(1)	-(1)
Poly iso-butyl methacrylate (PIBMA)	9011-15-8	-	30.9	-0.060^(b)	-	-	-	-	20.0	18.3	4.9	6.3	9.4
Poly iso-butyl methacrylate (PIBMA)			0.00(2)							2.11(3)	0.93(3)	5.12(3)	2.10(3)
Paraffin	8002-74-2	24.8	27.9	-0.060^(c)	109.3	108.5	96.0	11.0	-	-	-	-	-
Paraffin		6.53(3)	3.96(12)		1.84(2)	2.12(2)	-(1)	-(1)
Polyvinyl proprionate	25035-84-1	-	34.0	-0.072^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl proprionate			-(1)
Polyvinyl hexadecanoate	-	-	30.9	-0.066^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl hexadecanoate			-(1)
Polyvinyl butyrate	-	-	31.1	-0.070^(c)	-	-	-	-	-	-	-	-	-
Polyvinyl butyrate			-(1)
Polyvinyl acetate (PVA)	9003-20-7	35.3	38.5	-0.066^(b)	60.6	-	-	-	25.7	20.9	11.3	9.7	13.7
Polyvinyl acetate (PVA)		2.08(3)	2.75(14)		-(1)					-(1)	-(1)	-(1)	-(1)
Polystyrene (PS)	9003-53-6	34.0	38.3	-0.072^(b)	85.3	88.5	81.8	10.0	23.9	22.8	5.8	4.3	12.7
Polystyrene (PS)		4.27(18)	5.23(32)		6.08(8)	5.75(15)	3.86(4)	2.65(3)		-(1)	-(1)	-(1)	-(1)
Poly n-propyl methacrylate	2210-79-9	32.0	33.2	-0.065^(c)	-	-	-	-	-	-	-	-	-
Poly n-propyl methacrylate		-(1)	-(1)
Polymethyl acrylate (PMA)	25087-26-7	38.0	39.8	-0.070^(c)	-	-	-	-	-	-	-	-	-
Polymethyl acrylate (PMA)		4.24(2)	2.21(9)
Polyethylene terephthalate (PET)	25038-59-9	39.0	44.0	-0.065^(c)	72.0	73.0	54.5	20.0	20.8	18.7	6.3	6.7	6.5
Polyethylene terephthalate (PET)		5.71(11)	3.85(28)		6.33(17)	7.32(17)	5.77(8)	11.0(8)		1.25(8)	2.03(8)	2.80(8)	3.36(8)
Poly 2-ethylhexyl acrylate	9003-77-4	31.0	29.7	-0.070^(c)	-	-	-	-	-	-	-	-	-
Poly 2-ethylhexyl acrylate		-(1)	0.71(2)
Polyethyl methacrylate (PEMA)	9003-42-3	32.8	34.0	-0.070^(c)	-	-	-	-	20.0	17.5	8.5	4.7	9.6
Polyethyl methacrylate (PEMA)		0.90(4)	2.50(7)							1.34(3)	0.62(3)	3.82(3)	1.99(3)
Polyethyl acrylate (PEA)	9003-32-1	34.0	35.1	-0.070^(c)	-	-	-	-	-	-	-	-	-
Polyethyl acrylate (PEA)		1.41(2)	1.47(6)
Polydiethylsiloxane (PDES)	63148-61-8	-	25.7	-0.073^(c)	-	-	-	-	-	-	-	-	-
Polydiethylsiloxane (PDES)			-(1)
Polychlorotrifluoroethylene (PCTFE)	9002-83-9	30.8	30.7	-0.067^(c)	90.0	104.0	72.0	32.0	16.5	15.6	2.5	4.7	5.8
Polychlorotrifluoroethylene (PCTFE)		1.34(4)	3.79(7)		-(1)	0.00(2)	7.07(2)	7.07(2)		2.10(3)	1.46(3)	2.44(3)	1.56(3)
Poly n-butyl acrylate	9003-49-0	29.5	32.8	-0.070^(c)	-	-	-	-	-	-	-	-	-
Poly n-butyl acrylate		2.12(2)	1.82(3)
Nylon 6,6	32131-17-2	42.2	44.3	-0.065^(c)	67.6	69.3	40.9	27.6	25.8	17.2	9.9	16.5	4.4
Nylon 6,6		4.50(12)	3.62(18)		4.94(7)	2.91(5)	-(1)	-(1)		1.11	1.10	6.80	1.24
Hexatriacontane	630-06-8	20.6	22.8	-0.066^(c)	108.2	109.0	-	-	-	-	-	-	-
Hexatriacontane		1.30(6)	5.03(9)		4.03(2)	-(1)
Polypropylene isophthalate	-	-	49.3	-0.083^(c)	-	-	-	-	-	-	-	-	-
Polypropylene isophthalate			-(1)
Polypropylene glycol (PPG, polypropylene oxide)	25322-69-4	32.0	30.6	-0.079^(b)	-	-	-	-	-	-	-	-	-
Polypropylene glycol (PPG, polypropylene oxide)		-(1)	2.36(7)
Polymethyl methacrylate (PMMA, acrylic, plexiglas)	9011-14-7	37.5	41.8	-0.076^(b)	69.1	74.7	54.2	18.4	21.3	17.9	10.1	5.4	11.0
Polymethyl methacrylate (PMMA, acrylic, plexiglas)		4.68(12)	3.63(38)		6.08(17)	10.2(8)	5.44(2)	1.98(2)		1.37(5)	4.46(5)	3.73(5)	4.63(5)
Polybutylene isophthalate	-	-	47.8	-0.080^(c)	-	-	-	-	-	-	-	-	-
Polybutylene isophthalate			-(1)
Eicosane	112-95-8	-	28.9	-0.0833^(c)	-	-	-	-	-	-	-	-	-
Eicosane			-(1)
Polychloroprene	9010-98-4	38.0	40.9	-0.086^(b)	-	-	-	-	-	-	-	-	-
Polychloroprene		0.00(2)	3.63(7)
Polyethylene oxide (PEO, PEG, polyethylene glycol)	25322-68-3	43.0	43.1	-0.095^(c)	63.0	-	-	-	-	-	-	-	-
Polyethylene oxide (PEO, PEG, polyethylene glycol)		-(1)	2.07(16)		-(1)
Polybutadiene	9003-17-2	29.3	45.9	-0.144^(d)	96.0	-	-	-	18.0	17.5	2.3	3.4	6.6
Polybutadiene		3.79(3)	3.89(2)	-0.110^(e)	1.41(2)					-(1)	-(1)	-(1)	-(1)

(a) Atactic PP CAS #9003-08-0; isotactic PP CAS #25085-53-4.

(b) S. Wu, J. Macromol. Sci., C10, 1 (1974).

(c) S. Wu, in Polymer Handbook, 3rd Ed., J. Brandrup and E.H. Immergut, eds., Wiley-Interscience, New York, NY, 1989, p. VI: 414-426.

(d) Polybutadiene data for carboxyl end group; S. Wu, in Polymer Handbook, 3rd Ed., J. Brandrup and E.H. Immergut, eds., Wiley-Interscience, New York, NY, 1989, p. VI: 414-426.

(e) Polybutadiene data for methyl ester end group; S. Wu, in Polymer Handbook, 3rd Ed., J. Brandrup and E.H. Immergut, eds., Wiley-Interscience, New York, NY, 1989, p. VI: 414-426.

(f) Aluminum foil, while obviously not a polymer, is included due to its widespread use in package converting and other industries.

⁽¹⁾ Names which are most widely used to describe the material or family of materials (e.g., polyurethanes and epoxies) at hand are preferred here. Commonly used acronyms and synonyms are also shown.

⁽²⁾ CAS (Chemical Abstract Series) numbers are shown where available. In a number of instances, more than one CAS number is assigned to a given polymer — in some cases the details and nuances of these divergences are not at all clear. We have tried to reference the CAS number which appears to have the widest use with reference to the solid state properties of the given polymer.

⁽³⁾ γ_c: Critical surface tension in mJ/m² (equivalent to dynes/cm), generally determined by the Zisman method (regression of the cosine of the contact angle), or by the wetting tension method (using solutions of 2-ethoxyethanol and formamide, per ASTM Std. D-2578).

⁽⁴⁾ γ_s: Surface free energy in mJ/m² (equivalent to dynes/cm), as measured, estimated, and calculated by a wide variety of methods and theories.

⁽⁵⁾ dγ/dt: Change in surface energy in mJ/m² (equivalent to dynes/cm) per degree Kelvin (or Celsius).

⁽⁶⁾ θ_W^Y: Equilibrium (or Young's) contact angle with water, in degrees.

⁽⁷⁾ θ_W^A: Advancing contact angle with water, in degrees.

⁽⁸⁾ θ_W^R: Retreating contact angle with water, in degrees.

⁽⁹⁾ dθ_W: Contact angle hysteresis (difference between advancing and retreating) with water, in degrees.

⁽¹⁰⁾ δ: Total Hansen solubility parameter (square root of the sum of squares of the average values for dispersion, polar, and hydrogen bonding components), in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹¹⁾ δ_D: Hansen dispersion solubility parameter, in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹²⁾ δ_P: Hansen polar solubility parameter, in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹³⁾ δ_H: Hansen hydrogen bonding solubility parameter, in MPa^1/2 (equivalent to joules/cubic centimeter; 2.0455 x (cal/cc)^1/2) @ 20-25^oC (293.15-298.15 K). All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.

⁽¹⁴⁾ R_o: Interaction radius. All data from Hansen Solubility Parameters: A User's Handbook, 2nd Ed., C.M. Hansen, CRC Press, Boca Raton, FL, 2007.